Since I only have 2 chars (oh well..), only going to write for 2 classes based off my experience in PvE.
From 1 to 5:
1 = not useful/close to zero usefulness
2 = very little use
3 = okay-ish to use; not good, not bad
4 = potentially be important at higher level
5 = very useful, used all the time
Psychic: (up to level 39)
*Aqua Impact = 5
*Spirit Blast = 5
*Black Voodoo = 5
*White Voodoo = 3
*Soul of Vengeance = 3
*Tideform = 1
*Torrent = 1
*Landslide = 5
*Bubble of Life = 4
*Aqua Cannon = 4
*Sand Trap = 1
*Earthen Spirit = 4
*Aqua Spirit = 4
*Soul of Stunning = 2
*Diminished Vigor = 2
*Glacial Shard = 4
*Sandburst Blast = 4
*Soul of Silence = 3
Mystic: (up to level 39)
*Nature's Vengeance = 5
*Break in The Clouds = 5
*Swirling Mist = 1
*Devil Chihyu = 5
*Heal Summon = 5
*Falling Petals = 4
*Punishing Sting = 1
*Verdant Shell = 5
*Absorb Soul = 4
*Ressurect = 5
*Transference = ? (depends on summon: Chihyu = 2, Mistress = 5, Savy = 4, CL = 1)
*Befuddling Creeper = 2
*Storm Mistress = 4
*Spidervine = 2
*Lysing = 2
*Salvation Emerges = 4
*Listless Blossom = 2
*Gale Force = 4
*Comforting Mist = 4
*Healing Herb = 3
*Wood Mastery = 4
L> Mel Mel to rate her class skills
just need up to 39